2 PREPARATION, ACTIVE SUBSTANCE AND RELEVANT CHEMICAL
Ozone used for this system as an Active Substance has strong oxidizing property and is effective for disinfecting aquatic organisms. Its half-life period in the water (seawater, for instance) is as short as 5.8 seconds and Ozone remains there for a very short term. Therefore, no Ozone remains in the ballast water when discharged. In the seawater, by the reaction of Ozone and bromide ion, bromate is generated. Bromate ion also has a strong oxidizing property and contributes to disinfecting. The half-life period of bromate ion is on an average 12 hours which is longer than that of Ozone and impact on the environment by discharged ballast is a matter of concern.
Active Substance and relevant chemical used in this application is as shown in Table 3.
Table 3. |
Definition of Active Substance and Relevant chemical |
|
Seawater |
Fresh water |
Active Substance |
Ozone |
Ozone |
Relevant chemical |
Bromate ion |
- |
|
2.1 Preparation
Ozone as an Active Substance is produced by a generator provided on board. Since this process is not a commercial preparation using additives, etc., it is not described in this application form.
2.2 Active Substance
In this application form, Ozone is defined as an Active Substance. Ozone exists in oxygen (raw material) at a ratio of 6 to 12%. Therefore, when it is used for treating the ballast water, it is in a state of Ozone gas. Components of Ozone gas are shown in Table 4.
Table 4. Components of Ozone Gas
Name of substance |
GAS number |
Ratio |
Ozone |
10028-15-6 |
6〜12v/v% |
Oxygen |
7782-44-7 |
80〜88v/v% |
Nitrogen |
7727-37-9 |
2〜3v/v% |
Argon |
7440-37-1 |
4〜5v/v% |
|
2.3 Relevant chemical
In this application form, bromate ion generated during treatment of the ballast water of the seawater is defined as a relevant chemical.
Products generated by the reaction between Ozone and bromate ion in the seawater are hypobromous acid ion, hypobromous acid and bromate ion. Ratio of their existence varies under the influence of pH. Among these products, only the bromate ion as generated in the presumable pH range of 5 to 8 in the ballast water. Generally bromide ion accounts for 60 mg/L in the seawater but 0.1 mg/L or below in the fresh water of rivers, etc. Therefore, the volume of bromate ion generated when Ozone of 4 mg/L (the maximum feeding ratio in this system) is added, makes a substantial difference between the seawater and fresh water. The volume of bromate ion (measured as value of oxidant) when Ozone of 4 mg/L is added into the seawater is about 1.6 mg/L in 2 days (see section 8, Toxicity testing of the treated ballast water). In a short navigation, however, this concentration of the ballast water discharged may be potentially higher under the influence of the water quality or water temperature. For this reason, bromate ion was defined as a relevant chemical in the seawater. In the fresh waters, on the other hand, the volume generated is on the level of ppb and the influence on the environment may be actually ignored and bromate ion is not defined as a relevant chemical.
2.4 Physical and chemical properties of Active Substance and relevant chemical
Physical and chemical properties of Ozone and bromate ion and ballast water after being treated with this system are shown in Table 5.
Table 5. |
Physical and Chemical Properties of Ozone, Bromate ion and Ballast Water |
Physical property |
Ozone |
Bromate ion (Potassium bromate) |
Ballast water |
CAS number |
10028-15-6 |
7789-38-0 |
- |
Molecule weight |
48.02) |
167.0 |
- |
Liquid concentration |
1358g/L
(at -112℃)3) |
- |
- |
Evaporation heat |
15.2kJ/moL3) |
- |
- |
Melting point |
-193℃2) |
- |
- |
Boiling point |
-112℃2) |
- |
- |
Flammability |
Non-combustible but promotes burning of other substances. No. inflammability to liquid2). |
- |
- |
Density (20℃) |
2.144g/L (N.T.P)
(at 0℃, 101kPa)3) |
- |
- |
Vapour pressure
(20℃; Pa) |
>1 atm4) |
- |
- |
Vapour density (air=1) |
1.62)
(air=1) |
- |
- |
Water solubility |
0.1g/100mL
(at 0℃)2) |
7.5g/100ml(25℃) |
- |
pH in solution |
- |
- |
Aprox. 5-8 |
Dissociation constant (pKa) |
Definition for liquid; no relation with gas. |
8.62 |
- |
Oxidation reduction potential |
2.07V3,5) |
- |
- |
Corrosivity to Meterial |
Yes |
Yes |
No |
Reactivity to container material |
Yes |
- |
- |
Auto ignition temperature (℃) |
Noncombustible but promotes burning of other substances. Various reactions may cause a fire or explosion.2) |
- |
- |
Explosive Properties |
May cause a fire or explosion when heated or coming in contact with a combustible material (alkene, ether)2) |
- |
- |
Oxidizing properties |
Yes |
- |
- |
Surface tension |
3.84x10-2N/mm
(at -183℃)3) |
- |
- |
Viscosity |
1.57x10-3Pa.s
(at -183℃)3) |
66.6〜67.6※ |
0.01Pa.s |
Thermal stability and breakdown product |
Oxygen |
- |
- |
Other physical and Chemical property |
Nothing of noteworthy |
Oxidizing property |
Nothing of noteworty |
|
※ Value assuming the water coefficient of viscosity at 0℃ to be 100 (density, 14.02〜34.64wt%)
-: data not required
|
2.5 Laws and regulations for Active Substance and relevant chemical
2.5.1 Laws and regulation for Ozone
2.5.1.1 Regulation for Ozone concentration dissolved in water
There exist regulations on Ozone concentration for the water of the swimming pools in Germany, the European Union, Italy, etc. In the case of Germany, DIN Specification regulates the residual Ozone concentration as lower than 0.5mg/L and also the corresponding residual chlorine concentration as a different value.
2.5.1.2 Standard environmental concentration
In Japan, Ozone is regulated as a constituent of oxidant or photochemical oxidant. Standard value (value permitted in an hour) under the Basic Environment Law and the Air Pollution Control Act is 0.06ppm and O.l2ppm respectively. United States environmental standards are shown in Table 66),7),8).
Table 6. United States Environmental Standards
State |
Classification |
Standard Value |
State of New York |
Area of small classification unit, I, II |
0.05ppm/24hr (average) |
Area of small classification unit, III, IV |
0.1ppm/24hr (average) |
Statea of California |
Highest harmful concentration |
0.15ppm/1hr |
City of Los Angeles |
First warning |
0.5ppm or higher |
|
2.5.2 Laws and regulations for bromate ion
WHO determined the recommended value on bromate ion in the Drinking-water Quality Guidelines in 1993. The tentative value of the Guidelines was 25μg/1.10),11)
In the 1998 revision of the universal drinking water standard in the European Union, the standard bromic acid values were determined to be 25μg/1 by 2OO3 and 1Oμg/1 by 2OO8.
2.6 Information on application
Ozone is used as a disinfector for the city water, hygiene materials, breaching agent of agricultural chemicals at the stage of manufacture, compound intermediate of chemical compound raw materials, etc.
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