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Chapter 6
Materials of construction, protective linings and coatings
6.1 Structural materials used for tank construction, together with associated piping, pumps, valves, vents and their jointing materials, shall be suitable at the temperature and pressure for the cargo to be carried in accordance with recognized standards. Steel is assumed to be the normal material of construction.
6.2 The shipyard is responsible for providing compatibility information to the ship operator and/or master. This must be done in a timely manner before delivery of the ship or on completion of a relevant modification of the material of construction.
6.3 Where applicable, the following should be taken into account in selecting the material of construction:
.1 notch ductility at the operating temperature;
.2 corrosive effect of the cargo; and
.3 possibility of hazardous reactions between the cargo and the material of construction.
6.4 The shipper of the cargo is responsible for providing compatibility information to the ship operator and/or master. This must be done in a timely manner before transportation of the product. The cargo shall be compatible with all materials of construction such that:
.1 no damage to the integrity of the materials of construction is incurred; and/or
.2 no hazardous, or potentially hazardous reaction is created.
6.5 When a product is submitted to IMO for evaluation, and where compatibility of the product with materials referred to in paragraph 6.1 renders special requirements, the BLG Product Data Reporting form shall provide information on the required materials of construction. These requirements shall be reflected in chapter 15 and consequentially be referred to in column o of chapter 17. The reporting form shall also indicate if no special requirements are necesary. The producer of the product is responsible for providing the correct information.
Chapter 7
Cargo temperature control
7.1 General
7.1.1 When provided, any cargo heating or cooling systems shall be constructed, fitted and tested to the satisfaction of the Administration. Materials used in the construction of temperature-control systems shall be suitable for use with the product intended to be carried.
7.1.2 Heating or cooling media shall be of a type approved for use with the specific cargo. Consideration shall be given to the surface temperature of heating coils or ducts to avoid dangerous reactions from localized overheating or overcooling of cargo. (See also 15.13.6.)
7.1.3 Heating or cooling systems shall be provided with valves to isolate the system for each tank and to allow manual regulation of flow.
7.1.4 In any heating or cooling system, means shall be provided to ensure that, when in any condition other than empty, a higher pressure can be maintained within the system than the maximum pressure head that could be exerted by the cargo tank contents on the system.
7.1.5 Means shall be provided for measuring the cargo temperature.
.1 The means for measuring the cargo temperature shall be of restricted or closed type, respectively, when a restricted or closed gauging device is required for individual substances, as shown in column j in the table of chapter 17.
.2 A restricted temperature-measuring device is subject to the definition for a restricted gauging device in 13.1.1.2 (e.g. a portable thermometer lowered inside a gauge tube of the restricted type).
.3 A closed temperature-measuring device is subject to the definition for a closed gauging device in 13.1.1.3 (e.g. a remote-reading thermometer of which the sensor is installed in the tank).
.4 When overheating or overcooling could result in a dangerous condition, an alarm system which monitors the cargo temperature shall be provided. (See also operational requirements in 16.6.)
7.1.6 When products for which 15.12, 15.12.1 or 15.12.3 are listed in column o in the table of chapter 17 are being heated or cooled, the heating or cooling medium shall operate in a circuit:
.1 which is independent of other ship's services, except for another cargo heating or cooling system, and which does not enter the machinery space; or
.2 which is external to the tank carrying toxic products; or
.3 where the medium is sampled to check for the presence of cargo before it is recirculated to other services of the ship or into the machinery space. The sampling equipment shall be located within the cargo area and be capable of detecting the presence of any toxic cargo being heated or cooled. Where this method is used, the coil return shall be tested not only at the commencement of heating or cooling of a toxic product, but also on the first occasion the coil is used subsequent to having carried an unheated or uncooled toxic cargo.
7.2 Additional requirements
For certain products, additional requirements contained in chapter 15 are shown in column o in the table of chapter 17.
Chapter 8
Cargo tank venting and gas-freeing arrangements
8.1 Application
8.1.1 Unless expressly provided otherwise, this chapter applies to ships constructed on or after 1 January 1994.
8.1.2 Ships constructed before 1 January 1994 shall comply with the requirements of chapter 8 of this Code which were in force prior to the said date.
8.1.3 For the purpose of this regulation, the term .ship constructed. is as defined in SOLAS regulation II-1/1.3.1.
8.1.4 Ships constructed on or after 1 July 1986 but before 1 January 1994 which fully comply with the requirements of the Code applicable at that time may be regarded as complying with the requirements of SOLAS regulations II-2/4.5.3, 4.5.6 to 4.5.8, 4.5.10 and 11.6.
8.1.5 For ships to which the Code applies, the requirements of this chapter shall apply in lieu of SOLAS regulations II-2/4.5.3 and 4.5.6.
8.1.6 Ships constructed on or after 1 July 1986, but before 1 July 2002 shall comply with the requirements of 8.3.3.
8.2 Cargo tank venting
8.2.1 All cargo tanks shall be provided with a venting system appropriate to the cargo being carried and these systems shall be independent of the air pipes and venting systems of all other compartments of the ship. Tank venting systems shall be designed so as to minimize the possibility of cargo vapour accumulating about the decks, entering accommodation, service and machinery spaces and control stations and, in the case of flammable vapours, entering or collecting in spaces or areas containing sources of ignition. Tank venting systems shall be arranged to prevent entrance of water into the cargo tanks and, at the same time, vent outlets shall direct the vapour discharge upwards in the form of unimpeded jets.
8.2.2 The venting systems shall be connected to the top of each cargo tank and as far as practicable the cargo vent lines shall be self-draining back to the cargo tanks under all normal operational conditions of list and trim. Where it is necessary to drain venting systems above the level of any pressure/vacuum valve, capped or plugged drain cocks shall be provided.
8.2.3 Provision shall be made to ensure that the liquid head in any tank does not exceed the design head of the tank. Suitable high-level alarms, overflow control systems or spill valves, together with gauging and tank filling procedures, may be accepted for this purpose. Where the means of limiting cargo tank overpressure includes an automatic closing valve, the valve shall comply with the appropriate provisions of 15.19.
8.2.4 Tank venting systems shall be designed and operated so as to ensure that neither pressure nor vacuum created in the cargo tanks during loading or unloading exceeds tank design parameters. The main factors to be considered in the sizing of a tank venting system are as follows:
.1 design loading and unloading rate;
.2 gas evolution during loading: this shall be taken account of by multiplying the maximum loading rate by a factor of at least 1.25;
.3 density of the cargo vapour mixture;
.4 pressure loss in vent piping and across valves and fittings; and
.5 pressure/vacuum settings of relief devices.
8.2.5 Tank vent piping connected to cargo tanks of corrosion-resistant material, or to tanks which are lined or coated to handle special cargoes as required by the Code, shall be similarly lined or coated or constructed of corrosion-resistant material.
8.2.6 The master shall be provided with the maximum permissible loading and unloading rates for each tank or group of tanks consistent with the design of the venting systems.
8.3 Types of tank venting systems
8.3.1 An open tank venting system is a system which offers no restriction except for friction losses to the free flow of cargo vapours to and from the cargo tanks during normal operations. An open venting system may consist of individual vents from each tank, or such individual vents may be combined into a common header or headers, with due regard to cargo segregation. In no case shall shutoff valves be fitted either to the individual vents or to the header.
8.3.2 A controlled tank venting system is a system in which pressure- and vacuum-relief valves or pressure/vacuum valves are fitted to each tank to limit the pressure or vacuum in the tank. A controlled venting system may consist of individual vents from each tank or such individual vents on the pressure side only as may be combined into a common header or headers, with due regard to cargo segregation. In no case shall shut-off valves be fitted either above or below pressure- or vacuum-relief valves or pressure/vacuum valves. Provision may be made for bypassing a pressure- or vacuum-relief valve or pressure/vacuum valve under certain operating conditions provided that the requirement of 8.3.6 is maintained and that there is suitable indication to show whether or not the valve is bypassed.
8.3.3 Controlled tank venting systems shall consist of a primary and a secondary means of allowing full flow relief of vapour to prevent over-pressure or under-pressure in the event of failure of one means. Alternatively, the secondary means may consist of pressure sensors fitted in each tank with a monitoring system in the ship's cargo control room or position from which cargo operations are normally carried out. Such monitoring equipment shall also provide an alarm facility which is activated by detection of over-pressure or under-pressure conditions within a tank.
8.3.4 The position of vent outlets of a controlled tank venting system shall be arranged:
.1 at a height of not less than 6 m above the weather deck or above a raised walkway if fitted within 4 m of the raised walkway; and
.2 at a distance of at least 10 m measured horizontally from the nearest air intake or opening to accommodation, service and machinery spaces and ignition sources.
8.3.5 The vent outlet height referred to in 8.3.4.1 may be reduced to 3 m above the deck or a raised walkway, as applicable, provided that high-velocity venting valves of an approved type, directing the vapour/air mixture upwards in an unimpeded jet with an exit velocity of at least 30 m/s, are fitted.
8.3.6 Controlled tank venting systems fitted to tanks to be used for cargoes having a flashpoint not exceeding 60℃ (closed-cup test) shall be provided with devices to prevent the passage of flame into the cargo tanks. The design, testing and locating of the devices shall comply with the requirements of the Administration, which shall contain at least the standards adopted by the Organization.
8.3.7 In designing venting systems and in the selection of devices to prevent the passage of flame for incorporation into the tank venting system, due attention shall be paid to the possibility of the blockage of these systems and fittings by, for example, the freezing of cargo vapour, polymer build-up, atmospheric dust or icing up in adverse weather conditions. In this context it shall be noted that flame arresters and flame screens are more susceptible to blockage. Provisions shall be made such that the system and fittings may be inspected, operationally checked, cleaned or renewed as applicable.
8.3.8 Reference in 8.3.1 and 8.3.2 to the use of shutoff valves in the venting lines shall be interpreted to extend to all other means of stoppage, including spectacle blanks and blank flanges.
8.4 Venting requirements for individual products
Venting requirements for individual products are shown in column g, and additional requirements in column o in the table of chapter 17.
8.5 Cargo tank gas-freeing
8.5.1 The arrangements for gas-freeing cargo tanks used for cargoes other than those for which open venting is permitted shall be such as to minimize the hazards due to the dispersal of flammable or toxic vapours in the atmosphere and to flammable or toxic vapour mixtures in a cargo tank. Accordingly, gas-freeing operations shall be carried out such that vapour is initially discharged:
.1 through the vent outlets specified in 8.3.4 and 8.3.5; or
.2 through outlets at least 2 m above the cargo tank deck level with a vertical exit velocity of at least 30 m/s maintained during the gas-freeing operation; or
.3 through outlets at least 2 m above the cargo tank deck level with a vertical exit velocity of at least 20 m/s which are protected by suitable devices to prevent the passage of flame.
When the flammable vapour concentration at the outlets has been reduced to 30% of the lower flammable limit and, in the case of a toxic product, the vapour concentration does not present a significant health hazard, gas-freeing may thereafter be continued at cargo tank deck level.
8.5.2 The outlets referred to in 8.5.1.2 and 8.5.1.3 may be fixed or portable pipes.
8.5.3 In designing a gas-freeing system in conformity with 8.5.1, particularly in order to achieve the required exit velocities of 8.5.1.2 and 8.5.1.3, due consideration shall be given to the following:
.1 materials of construction of system;
.2 time to gas-free;
.3 flow characteristics of fans to be used;
.4 the pressure losses created by ducting, piping, cargo tank inlets and outlets;
.5 the pressure achievable in the fan driving medium (e.g. water or compressed air); and
.6 the densities of the cargo vapour/air mixtures for the range of cargoes to be carried.
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