* Kawasaki heavy Industries, Ltd. 1-1-3 Higashikawasaki-cho, Chuo-ku, Kobe, Japan
**Japan Marine Science and Technology Center 2-15 Natsushima-cho, Yokosuka, Japan
Key Words: Carbon dioxide absorber, Molecular Sieve, Under water laboratory,Saturation diving, Hyperbaric circumstances
Abstract
In hyperbaric spaces like an underwater laboratory to which the conception of saturation diving is applied, a hyperbaric environmental control of temperature, humidity, partial pressure of O2 and CO2 in the environment gas is necessary and removal of carbon dioxide(CO2)is especially important.
In the present hyperbaric circumstances, the disposal CO2 absorbents are used for this purpose, which obliges the habitants in the underwater laboratory to periodically exchange theCO2 absorbents, and storage of such unused and used CO2 absorbents requires a great space in the laboratory. For this reason, it is desired to develop such a CO2 remover that uses a reusable CO2 adsorbent.
This paper describes an outline of the reusable CO2 adsorbent used in the CO2 remover, as well as the results of its experimental study for its practical use.
In the experimental study, we have selected three kinds of molecular sieves(MS) for CO2 absorbent, and measured the CO2 equilibrium adsorption amount. From this we have ascertained that the equilibrium adsorption amount in low pressure CO2 [0.005ATA(3.8mmHg) ] , which is the target pressure in our research, can be approximated by Langmuir equation.
Then, we have carried out CO2 breakthrough test on two kinds of adsorbcnts in the hyperbaric circumstances of 4ATA. One is the MS selected as a result of the equilibrium adsorption amount measurement and the other is solid amine(SA) which is used as a CO2 adsorbent in the atmosphere.
MS and SA have been tested by use of carrier gases, N2 and He, in the hyperbaric circumstances of 4ATA(partial pressure of CO2:0.005ATA). As a result, the following have been ascertained:
(I) MS is higher than SA in the CO2 adsorption efficiency.
(2)The adsorption efficiency of MS depends on carrier gas. The case of He as carrier gas is higher than that of N2 in the adsorption efficiency.